Tuesday, December 29, 2020

Mass Spectrometry

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Mass spectrometry is a powerful analytical technique used to quantify known materials, to identify unknown compounds within a sample, and to elucidate the structure and chemical properties of different molecules. The MS principle consists of ionizing chemical compounds to generate charged molecules or molecule fragments and measurement of their mass-to-charge ratios by using the one of a variety of techniques.

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Polymerization Catalyst

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Polymerization, any process in which relatively small molecules, called monomers, combine chemically to produce a very large chain like or network molecule, called a polymer. Most polymerization catalysts are cationic complexes in the active form. The positive charge increases the Lewis acidity of the complex, while reducing the fraction of any dinuclear alkyl bridged complexes.

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Monday, December 28, 2020

Energy Conservation Chemistry

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Conservation of energy, principle of physics according to which the energy of interacting bodies or particles in a closed system remains constant. The first kind of energy to be recognized was kinetic energy, or energy of motion.

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Organic Optical Materials

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Advancements of lasers and optical fibers contributed to optical communications and optical disks for practical use. Organic nonlinear optical materials have high figures of merit for a variety of device applications, including frequency doubling, electro-optic modulation and switching, and real time holography using the photorefractive effect.

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Pollutant Evaluation

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The pollution control situation of the sewage systems across can be divided into the two major sewage systems, namely, industrial area sewage and public community sewage. Situations in which a conversion of traffic control type is applied to an existing intersection are frequent in real networks, and it is interesting to evaluate how pollutant emissions may change as a result. The increasing availability of micro simulation software and emission models makes it now possible to conduct such detailed analyses at an operational level.

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Pollution Indicator

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Pollution is known as any undesirable changes in the physical, chemical, and biological features of a given ecosystem. Biological, chemical, and physical pollution indicators are classified as descriptive, performance, efficiency, policy effectiveness, and total welfare ones. However, recording all variable in a given ecosystem necessitates the amalgamating of biological, chemical, and physical pollution indicators.

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Wednesday, December 23, 2020

Radiochemistry

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Radiochemistry is a scientific branch that studies the chemistry of radioactive materials and uses radioactive isotopes of the chemical elements to examine chemical reactions. The radiochemistry involved with the production and the chemical properties of radionuclides, the use of Radio chemicals, for example in the materials and material testing, determining the age or the radio medicine. Radioactivity or radioactive decay is a spontaneous transformation of nuclei of unstable nuclides to other nuclei, during which radioactive radiation is emitted.

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Coordination Polymers

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A coordination polymer is an inorganic or organometallic polymer structure containing metal cation centers linked by organic ligands. Coordination polymers are relevant to many fields such as organic and inorganic chemistry, biochemistry, materials science, electrochemistry, and pharmacology, having many potential applications. This interdisciplinary nature has led to extensive study in the past few decades. Coordination polymers can be classified in a number of different ways according to their structure and composition.

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Monday, December 21, 2020

Structural Organic Chemistry

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Structural formulas identify the location of chemical bonds between the atoms of a molecule.  Structural chemistry is concerned with valence, which determines how atoms combine in definite ratios and how this is related to the bond directions and bond lengths. Carbon compounds can be formulated with four covalent bonds to each carbon, regardless of whether the combination is with carbon or some other element. The two-electron bond is called a single bond. Compounds, in which two electrons from each of the carbon atoms are mutually shared, produce two two-electron bonds, which are called double bonds.

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Biophysical Chemistry

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Biophysical chemistry deals with bio macromolecules and their physical interactions. The inside and outside of living cells are full of biomolecules, from simple ones to sophisticated complex machineries, of which the collective interplay controls biological processes, such as cellular growth and differentiation. In living cells confinement, molecular crowding and heterogeneity of local environments play a major role in the action of biomolecules.

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Friday, December 18, 2020

Entrophy

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Entropy, the measure of a system’s thermal energy per unit temperature that is unavailable for doing useful work. Because work is obtained from ordered molecular motion, the amount of entropy is also a measure of the molecular disorder, or randomness, of a system.

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Monatomic

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A monatomic ion is an ion formed from a single atom. The charge on the ion is the difference between the number of protons and electrons. The thermodynamic behavior of a monatomic gas in the ordinary temperature range is extremely simple because it is free from the rotational and vibrational energy components characteristic of polyatomic gases; thus its heat capacity is independent of temperature and molecular weight, and its entropy depends only on temperature and molecular weight.

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Thursday, December 17, 2020

Theoretical Organic Chemistry

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The rapid growth of organic chemistry, however, makes the task of the reviser ever more difficult, and although an earnest attempt has undoubtedly been made to bring this classic up to date by the addition. Much material of purely historical significance might have been sacrificed; petroleum as an illuminant is relatively unimportant compared with its value as a motor fuel. The latter topic receives far too little attention, an omission which is all the more serious in view of the growing importance of the petroleum industry as a source of basic organic chemicals such as olefines, butadiene, isopropyl alcohol and acetone. No mention is made of the direct production of nitroparaffins from hydrocarbons, and subjects such as plastics and catalytic hydrogenation are given inadequate treatment.

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Metal Complex Chemistry

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A metal complex consists of a central metal atom or ion that is bonded to one or more ligands, which are ions or molecules that contain one or more pairs of electrons that can be shared with the metal.

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Wednesday, December 16, 2020

Electronic Properties

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Electrical property refers to the response of a material to an applied electric field. One of the principal characteristics of materials is their ability to conduct electrical current. The electrical conductivity of a metal is determined by the ease of movement of electrons past the atoms under the influence of an electric field. This movement is particularly easy in copper, silver, gold, and aluminum all of which are well-known conductors of electricity. The conductivity of a given metal is decreased by phenomena that deflect, or scatter, the moving electrons.

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Integrated Properties

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Integration is an important component of integral calculus which generally fetches a good number of questions in various competitive exams. Both indefinite and definite integration are interrelated and indefinite integration lays the groundwork for definite integral.

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Tuesday, December 15, 2020

Molecular Device Materials

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Molecular nanotechnology is an important branch of the nanosciences, exhibiting strong chemical appeal, besides encompassing most of the exciting aspects of nanomaterials, nanobiology and nanoelectronics. Molecular designing of materials and single molecule studies are opening wide possibilities of using molecular systems in electronic and photonic devices, as well as in technological applications based on molecular switching or molecular recognition. Several molecular based materials, derived from inorganic and metal-organic compounds.

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Electrochemical Materials

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Electrochemical materials are widely used in advanced technology such as electronics, energy and sensor applications. Electrochemical energy storage and conversion systems are becoming essential for electrified transportation, integration of intermittent renewable energy into grids, non-fossil and green fuel production, and many other energy or power applications. The electrode materials and structures, in addition to the liquid or solid electrolytes, play key roles in supporting a multitude of coupled physicochemical processes that include electronic, ionic, and diffusive transport in electrode and electrolyte phases, electrochemical reactions and material phase changes, as well as mechanical and thermal stresses, thus determining the storage energy density and power density, conversion efficiency, performance lifetime, and system cost and safety.

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Monday, December 14, 2020

Organometallic Chemistry

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Organometallic chemistry is the study of compounds containing, and reactions involving, metal-carbon bonds. The metal-carbon bond may be transient or temporary, but if one exists during a reaction or in a compound of interest, we’re squarely in the domain of organometallic chemistry. Organometallic compounds are typically discussed in terms of the metal as either main-group compounds or transition metal compounds.

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Bioinorganic Chemistry

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Bioinorganic chemistry is about the structure, function, mechanism and dynamics of biologically relevant metal complexes and metal-containing proteins. Investigators in this area try to understand what the function of a biological relevant metal site is, how it achieves its function and what factors dictate its function through studying either small metal complexes or metalloproteins.

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Sunday, December 13, 2020

Moderator Materials

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The moderator of a nuclear reactor is a substance that slows neutrons down. In traditional nuclear reactors, the moderator is the same thing as the coolant. Some materials are better at slowing down neutrons than others. Conservation of energy and momentum laws explain that a neutron cannot slow down much after a collision with a heavy nucleus, like a fuel atom. However, in a collision with Hydrogen, a neutron can in fact slow down very far. Imagine a ping-pong ball bouncing off a bowling ball, as opposed to the same Ping-Pong ball colliding with another ping-pong ball.  There are several different types of moderating materials, and each have places where they are used more effectively. Typically-used moderator materials include heavy water, light water, and graphite.

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Jet Engine Materials

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A jet engine is contained within a cowling, an extermal casing that opens outward, somewhat like a rounded automobile hood, to permit inspection and repair of the interior components. In aero-engines, the blade of the high pressure turbine was for a long time the highest of the high technology in the aero gas turbine, and despite the complexity of the modern fan blade, the challenge it provides does not reduce. The ability to run at increasingly high gas temperatures has resulted from a combination of material improvements and the development of more sophisticated arrangements for internal and external cooling.

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Thursday, December 10, 2020

Nuclear Materials

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Nuclear energy production requires materials that are very resistant under demanding environment: temperature, pressure and irradiation field. These materials act as barriers and their structural properties are investigated with emphasis on mechanical performance, durability, plasticity and stability.

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Shielding Materials

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Radiation shielding is imperative as radiation can be a serious concern in nuclear power facilities, industrial or medical x-ray systems, radioisotope projects, particle accelerator work, and a number of other circumstances. The process of regulating the effects and degree of penetration of radioactive rays varies according to the type of radiation involved.

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Wednesday, December 9, 2020

Superconducting Magnets

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Superconductors such as niobium-tin and niobium-titanium are used to make the coil windings for superconducting magnets. These two materials can be fabricated into wires and can withstand high magnetic fields. Typical construction of the coils is to embed a large number of fine filaments in a copper matrix. The solid copper gives mechanical stability and provides a path for the large currents in case the superconducting state is lost. These superconducting magnets must be cooled with liquid helium. Superconducting magnets can use solenoid geometries as do ordinary electromagnets.

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Nanocrystalline Materials

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Nanocrystalline materials are polycrystalline materials with grain sizes. Nanocrystalline materials can be prepared by inert gas-condensation, mechanical alloying, plasma deposition, spray conversion processing, and many other methods. The properties of nanocrystalline materials are very often superior to those of conventional polycrystalline coarse-grained materials. Nanocrystalline materials exhibit increased strength/hardness, enhanced diffusivity, improved ductility/toughness, reduced density, reduced elastic modulus, higher electrical resistivity, increased specific heat, higher thermal expansion coefficient, lower thermal conductivity, and superior soft magnetic properties in comparison to conventional coarse-grained materials.

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Tuesday, December 8, 2020

Ceramic Nanocomposites

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Nano composite material has broadened significantly to encompass a large variety of systems such as one-dimensional, two-dimensional, three-dimensional and amorphous materials, made of distinctly dissimilar components and mixed at the nanometer scale. Reducing the sizes of structural features in materials leads to a significant increase in the portion of surface/interface atoms. Interfaces provide a means to introduce non-homogeneity in the material. The properties of nano-composite materials depend not only on the properties of their individual parents but also on their morphology and interfacial characteristics. The nanocomposites find their use in various applications because of the improvements in the properties over the simpler structures.

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Molecular Engineering

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Molecular engineering is any means of manufacturing molecules. It may be used to create, on an extremely small scale, most typically one at a time, new molecules which may not exist in nature, or be stable beyond a very narrow range of conditions. Today this is an arduous process, requiring manual manipulation of molecules using such devices as a scanning tunneling microscope. Molecular engineering is highly interdisciplinary by nature, encompassing aspects of chemical engineering, materials science, bioengineering, electrical engineering, physics, mechanical engineering, and chemistry. There is also considerable overlap with nanotechnology, in that both are concerned with the behavior of materials on the scale of nanometers or smaller.

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Organic Crystals

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Crystalline materials in terms of structure and function; and second, to consider if and how such materials might eventually enter the realm of device applicability. The review therefore attempts to treat a relatively large number of examples including fundamental physical and electronic structure, single component and charge transfer complexes, physical properties of single crystalline materials, thin film and single crystal electronic and photonic devices, functional materials, and bio-inspired structures.

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Catalytic Materials

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Catalytic materials focusing on three demonstrator applications in selective C- C-coupling and C-C-cleavage reactions. Catalytic materials displaying multi-functionality and surface-structure-induced selectivity pattern in C-C-couplings are designed, synthesized, and tested in continuous mini plants. catalytic materials can be developed as nanostructures. Smaller particles or structures provide a higher specific surface area and hence more active sites. In addition, small particles or pores induce high O2 bubble binding affinity, which can enhance the H2O2 selectivity.

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Sunday, December 6, 2020

Organic Materials

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Organic materials on the mobility of various pollutants, including actinides, has been studied by several workers. organic materials, such as coal, natural gas, oil shale, tar sand, and crude oil, were exploited to produce a variety of hydrocarbon compounds in gas, liquid, and semisolid forms for many uses.

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Waveguides

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Waveguide, any of a class of devices that confines and directs the propagation of electromagnetic waves, such as radio waves, infrared rays, and visible light. Waveguides take many shapes and forms. Circular metallic tubes are appropriate for such applications as radar in which two sections of the waveguide must rotate with respect to one another. Coaxial cables are well suited for such long-distance transmission because the central conductor is shielded from external electrical noise by the outer conducting material.

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Friday, December 4, 2020

Metal Composites

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Metal matrix composites are a class of materials comprised of a metal fused with another substance. These two components appear in differing phases that are physically and chemically distinct. The base material is a metal matrix, while the other substance appears as fibres or particulates to work as reinforcing material. Some composites are built to have higher creep resistance than the pure metal counterparts. This reduces the risk of warping or deformation in the material, especially when exposed to welding or tensile stress with high temperature. Metal matrix composites work best in industries with a high risk of creep fatigue or sudden temperature changes. Metal matrix composites work well as components in transmission systems, gearboxes, engine parts and accessories, and other internal elements.

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Wood Composites

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Wood composites include a range of different derivative wood products, all of which are created by binding the strands, fibers or boards of wood together. It’s also known as manmade wood, manufactured board or engineered wood. Composite wood products can be used in a variety of different ways, including both home and industrial construction, and is often used to replace steel for joists and beams in building projects. While composite wood can be used in most applications traditionally using solid wood, it is also a popular material for making flat-pack furniture due to its low manufacturing costs and light weight properties.

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Thursday, December 3, 2020

Thermostructural Ceramics

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Thermo-structural behavior of ceramic components, in particular, mixtures of refractory materials with high thermal and mechanical performance. Ceramic matrix composites consist of a ceramic matrix reinforced with ceramic fibers. They have been designed to be used in severe environments. With respect to monolithic ceramics, CMCs are characterized by a non-linear strain mechanical behavior, a high resistance to crack propagation, a non-catastrophic failure and thus an improved reliability.

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Structural Ceramics

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Ceramic materials that demonstrate enhanced mechanical properties under demanding conditions. Because they serve as structural members, often being subjected to mechanical loading, they are given the name structural ceramics. The properties of ceramics are determined by the types of atoms present, the types of bonding between the atoms, and the way the atoms are packed together.

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Wednesday, December 2, 2020

Biocomposites

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Biocomposites are natural fibre-reinforced biopolymers. Biocomposites varies greatly throughout the literature with some definitions including composites composed of synthetic fibres or polymers. Biocomposites produced by reactive extrusion, the technology controlling the matrix-fibre interface, can be categorized as thermoplastic biocomposites, designated for injection moulding or extrusion. They can be processed with traditional equipment with some adjustments to process settings and no physical hardware modification. Many components such as the casings for computers, monitors, and mobile phone cases could be to a greater extent produced from biocomposite materials.

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Composite Materials

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Composites are materials made by combining two or more natural or artificial elements that are stronger as a team than as individual players. The component materials don’t completely blend or lose their individual identities; they combine and contribute their most useful traits to improve the outcome or final product. Composites are typically designed with a particular use in mind, such as added strength, efficiency or durability. The matrix protects the fibers from environmental and external damage and transfers the load between the fibers. Composites can be natural or synthetic. Wood, a natural composite, is a combination of cellulose or wood fibers and a substance called lignin. The fibers give wood its strength; lignin is the matrix or natural glue that binds and stabilizes them.

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Tuesday, December 1, 2020

Oxide Glasses

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Oxide glass is seriously considered for use as a containment matrix for high-level nuclear waste. The final decision will be based on investigations of the glass structure, leaching resistance and behavior under irradiation, notably the formation of helium or oxygen bubbles.

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Optical Glasses

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Optical glass is manufactured using different chemicals to enhance properties that are useful specifically for optics applications. Optical glass may contain a variety of additives, such as boric oxide, lead, zinc oxide, fluorite, and barium oxide to enhance its ability to transmit light within certain wavelengths. Depending on the chemical composition of the glass, different wavelengths of light, both visible and invisible, can be absorbed, transmitted, or refracted to achieve the desirable optical effect for a given application.

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